




The quest for a systematic arrangement of the elements started with the discovery of individual elements (see Discovery of Elements). By 1860 about 60 elements were known and a method was needed for organization. In fact many scientists made significant contributions that eventually enabled Mendeleev to construct his table. The periodic table did not end with Mendeleev but continued to take shape for the next 75 years.

The development of the periodic table begins with German
chemist Johann
Dobereiner (1780-1849) who grouped elements based on similarities.
Calcium (atomic weight 40), strontium (atomic weight 88), and barium (atomic
weight 137) possess similar chemical prepares. Dobereiner noticed
the atomic weight of strontium fell midway between the weights of calcium
and barium:
Ca
Sr Ba
(40 + 137) ÷ 2 = 88
40
88 137
Was this merely a coincidence or did some pattern to the
arrangement of the elements exist? Dobereiner noticed the same pattern
for the alkali metal triad (Li/Na/K) and the halogen triad (Cl/Br/I).
Li
Na K Cl
Br I
7
23 39
35 80 127
In 1829 Dobereiner proposed the Law of Triads: Middle
element in the triad had atomic weight that was the average of the other
two members. Soon other scientists found chemical relationships extended
beyond triads. Fluorine was added to Cl/Br/I group; sulfur, oxygen, selenium
and tellurium were grouped into a family; nitrogen, phosphorus, arsenic,
antimony, and bismuth were classified as another group.
First Periodic Table
It was a 19th century geologist who first recognized
periodicity in the physical properties of the elements. Alexandre
Beguyer de Chancourtois (1820-1886), professor of geology at the School
of Mines in Paris, published in 1862 a list of all the known elements.
The list was constructed as a helical graph wrapped around a cylinder--elements
with similar properties occupied positions on the same vertical line of
cylinder (the list also included some ions and compounds).
Using geological terms and published without the diagram, de Chancourtois
ideas were completely ignored until the work of Mendeleev.
Law of Octaves

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English chemist John
Newlands (1837-1898), having arranged the 62 known elements in order
of increasing atomic weights, noted that after interval of eight
elements similar physical/chemical properties reappeared. Newlands
was the first to formulate the concept of periodicity in the properties
of the chemical elements. In 1863 he wrote a paper
proposing the Law of Octaves: Elements exhibit similar behavior to the
eighth element following it in the table.
Mendeleev's Periodic Table
Then in 1869, Russian chemist Dimitri
Mendeleev (1834-1907) proposed
arranging elements by atomic weights and properties (Lothar
Meyer independently reached similar conclusion but published results
after Mendeleev). Mendeleev's periodic table of 1869 contained 17
columns with two partial periods of seven elements each (Li-F & Na-Cl)
followed by two nearly complete periods (K-Br &
Rb-I).
In 1871 Mendeleev revised the 17-group table with eight columns (the eighth group consisted of transition elements). This table exhibited similarities not only in small units such as the triads, but showed similarities in an entire network of vertical, horizontal, and diagonal relationships. The table contained gaps but Mendeleev predicted the discovery of new elements. In 1906, Mendeleev came within one vote of receiving the Nobel Prize in chemistry.

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Noble Gases
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Lord
Rayleigh (1842-1919) and William
Ramsey (1852-1916) greatly enhanced the periodic table by discovering
the "inert gases." In 1895 Rayleigh reported the discovery of a new
gaseous element named argon.
This element was chemically inert and did not fit any of the known periodic
groups. Ramsey followed by discovering the remainder of the inert gases
and positioning them in the periodic table. So by 1900, the periodic table
was taking shape with elements were arranged by atomic weight. For
example, 16g oxygen reacts with 40g calcium, 88g strontium, or 137g barium.
If oxygen used as the reference, then Ca/Sr/Ba assigned atomic weights
of 40, 88, and 137 respectively.
Rayleigh (physics) and Ramsey (chemistry) were awarded
Nobel prizes in 1904. The first inert gas compound
was made in 1962 (xenon tetrafluoride) and numerous compounds have followed
(see xenon compounds)--today
the group is more appropriately called the noble gases.
Moseley's Periodic Law
Soon after Rutherford's landmark experiment of discovering
the proton in 1911, Henry
Moseley (1887-1915) subjected known elements to x-rays.
He was able to derive the relationship between x-ray frequency and number
of protons. When Moseley arranged the elements according to increasing
atomic numbers and not atomic masses, some of the inconsistencies associated
with Mendeleev's table were eliminated. The modern periodic table is based
on Moseley's Periodic Law (atomic numbers). At age 28, Moseley was killed
in action during World War I and as a direct result Britain adopted the
policy of exempting scientists from fighting in wars. Shown
below is a periodic table from 1930:
Modern Periodic Table
The last major change to the periodic table resulted
from Glenn Seaborg's
work in the middle of the 20th century. Starting with plutonium in 1940,
Seaborg discovered transuranium
elements 94 to 102 and reconfigured the periodic table by placing the
lanthanide/actinide series at the bottom of the table. In 1951 Seaborg
was awarded the Nobel Prize in chemistry and element 106 was later named
seaborgium (Sg) in his honor.
Attention: New Additions to
Periodic Table![]()
WOMANIUM (WO)
Physical properties: Generally
soft and round in form. Boils at nothing and may freeze any time. Very
bitter if not used well.
Chemical properties: Very active
and highly unstable. Possesses strong affinity with gold, silver, platinum,
and precious stones. Violent when left alone. Turns slightly green when
placed next to a better specimen.
Usage: An extremely good catalyst
for dispersion of wealth.
Caution: Highly explosive in inexperienced
hands!
MANIUM (XY)
Physical properties: Solid at room
temperature but gets bent out of shape easily. Difficult to find a pure
sample. Due to rust, aging samples are unable to conduct electricity as
easily as young samples.
Chemical properties: Attempts to
bond with WO any chance it can get. Also tends to form strong bonds with
itself. Becomes explosive when mixed with Childrium for prolonged period
of time.
Usage: Possibly good methane source.
Caution: In the absence of WO,
this element rapidly decomposes and begins to smell.