Example
1: 2Na + S ®
Na2S
Na° ® Na+1
(oxidized)
S° ® S-2
(reduced)
Oxidation: 2Na
®
2Na+1
+ 2e-1
Reduction: S
+ 2e-1
®
S-2
Overall:
2Na + S ®2Na+1
+ S-2
Overall
equation is sum of oxidation/reduction equations (electrons always cancel).
Example
2: 2Al(s)
+ 3ZnCl2(aq) ®
AlCl3(aq) + 3Zn(s)
Here is a single substitution
with Al replacing Zn:
Al°®
Al+3
(oxidized)
Zn+2 ®
Zn° (reduced)
Cl-1 ®
Cl-1 (spectator
ion)
Oxidation: 2Al
®
2Al+3
+ 6e-1
Reduction: 3Zn+2
+ 6e-1 ®
3Zn
Overall:
2Al + 3Zn+2
®2Al+3
+ 3Zn
Next
we look at REDOX reactions taking place in water under acidic or basic
conditons.
For
acidic conditions, balance with H+1, H2O,
or H+1/H2O
For
basic conditions, balance with OH-1, H2O,
or OH-1/H2O
Oxidation & reduction always
go together but we begin with half reactions:
Example
3: AsH3
®
As
(acidic)
As-3 ®
As°
(oxidized)
AsH3®
As
+ 3H+1
+ 3e-1 (oxidation)
Example 4:
VO3-1®
V+2
(acidic)
V+5®
V+2
(reduced)
VO3-1®
V+2+
3H2O
VO3-1+
6H+1 + 3e-1
®
V+2
+
3H2O(reduction)
Example
5: U+4®
UO2+1
(acidic)
U+4+2H2O
®
UO2+1
U+4+
2H2O
®
UO2+1
+ 4H+1
+ 1e-1 (oxidation)
Example
6: MnO4-1®
Mn+2
(acidic)
MnO4-1 ®
Mn+2+
4H2O
MnO4-1+
8H+1 + 5e-1®
Mn+2
+ 4H2O
(reduction)
But oxidation always accompanies reduction reaction. We now look at full (overall) reactions.
Example
7: MnO4-1+
Br-1 ®
Mn+2
+ Br2
(acidic)
Mn+7®
Mn+2 (reduced)
Br-1 ®
Br° (oxidized)
Oxidation:
2Br-1®
Br2+
2e-1
Reduction:
MnO4-1+
8H+1 + 5e-1®
Mn+2+
4H2O
Multiply
oxidation by 5 and reduction by 2 (e-1
lost must equal e-1
gained):
[2Br-1
®
Br2+
2e-1]
5
[MnO4-1+
8H+1 + 5e-1®
Mn+2+
4H2O]2
Oxidation:
10Br-1®
5Br2+
10e-1
Reduction:
2MnO4-1+
16H+1 + 10e-1®
2Mn+2
+ 8H2O
Overall:
2MnO4-1+
16H+1 + 10Br-1®
2Mn+2
+ 5Br2 +
8H2O
Example
8: Co + NO3-1®
Co+3
+ NO2
(acidic)
Co° ® Co+3
(oxidized)
N+5 ®
N+4 (reduced)
Oxidation:
Co®
Co+3
+ 3e-1
Reduction:
[NO3-1+
2H+1 + 1e-1®
NO2
+ H2O]
3
Overall:
Co+
3NO3-1+
6H+1®
Co+3
+
3NO2 + 3H2O
For REDOX under
basic conditions, use OH-1/H2O
to balance or first balance under acidic conditions
followed by complete
neutralization of H+1
with OH-1.
Example
9: MnO4-1®
MnO2
(basic)
Mn+7 ®
Mn+4 (reduced)
MnO4-1 +
4H+1 + 3e-1®
MnO2+
2H2O
(4H+1
+
4OH-1 ®
4H2O)
+4OH-1
+4OH-1
MnO4-1+
4H2O + 3e-1
®
MnO2+
4OH-1+
2H2O (subtract
2H2O
from each side)
MnO4-1+
2H2O + 3e-1
®
MnO2+
4OH-1
Example
10: ClO-1®
Cl-1 (basic)
Cl+1 ®
Cl-1
(reduced)
ClO-1 +
2H+1 + 2e-1®Cl-1+
H2O
+2OH-1
+2OH-1
ClO-1
+ H2O + 2e-1®
Cl-1 +
2OH-1
Example
11: Br2®
2BrO3-1 (basic)
Br° ® Br+5
(oxidized)
Br2 + 6H2O
®
2BrO3-1 +
12H+1 + 10e-1
+12OH-1
+12OH-1
Br2
+12OH-1 ®
2BrO3-1 +
6H2O + 10e-1
Example
12: Sn ® Sn(OH)4-2
(basic)
Sn +
4OH-1® Sn(OH)4-2
+ 2e-1
(reduced)
Example
13: Al + S ®
HS-1 + Al(OH)3
(basic)
Al° ® Al+3
(oxidized)
S° ® S-2
(reduced)
Oxidation:
[Al + 3OH-1®
Al(OH)3+ 3e-1]2
Reduction:
S + H+1 + 2e-1®
HS-1
+OH-1
+OH-1
[S + H2O
+ 2e-1 ®
HS-1 + OH-1]3
Overall:
2Al + 3S + 3H2O
+ 3OH-1 ®
3HS-1 + 2Al(OH)3
Example
14: NO2-1
+ Al ® NH3
+ Al(OH)4-1 (basic)
Al° ® Al+3
(oxidized)
N+3 ®
N-3 (reduced)
Oxidation:
[Al + 4OH-1®
Al(OH)4-1 +
3e-1]2
Reduction: NO2-1
+ 7H+1 + 6e-1
® NH3+
2H2O
+7OH-1
+7OH-1
[NO2-1
+ 5H2O + 6e-1
® NH3+
7OH-1]
Overall:
2Al + NO2-1
+
5H2O +
OH-1®
2Al(OH)4-1 +
NH3