Oxidation: Loss of Electrons
    Reduction: Gain of Electrons
      Reduction & oxidation reactions go together and called REDOX reactions. We will write balanced oxidation/reduction/overall equations.
      In these equations charge as well as mass must be conserved! Conservation of charge maintained by adding electrons to right for oxidation
      and to left for reduction.

     Example 1:   2Na  +  S  ® Na2S
                          Na° ® Na+1  (oxidized)
                           S° ® S-2     (reduced)
     Oxidation:   2Na ® 2Na+1 + 2e-1
     Reduction:   S + 2e-1 ® S-2
     Overall:      2Na  +  S ®2Na+1 S-2
     Overall equation is sum of oxidation/reduction equations (electrons always cancel).

     Example 2:   2Al(s) + 3ZnCl2(aq) ® AlCl3(aq) + 3Zn(s)
     Here is a single substitution with Al replacing Zn:
                          Al°® Al+3   (oxidized)
                          Zn+2 ® Zn°  (reduced)
                          Cl-1 ® Cl-1   (spectator ion)
     Oxidation:   2Al ® 2Al+3 +  6e-1
     Reduction:  3Zn+2 + 6e-1 ® 3Zn
     Overall:      2Al  + 3Zn+2 ®2Al+3 + 3Zn

     Next we look at REDOX reactions taking place in water under acidic or basic conditons.
     For acidic conditions, balance with H+1, H2O, or H+1/H2O
     For basic conditions, balance with OH-1, H2O, or OH-1/H2O
     Oxidation & reduction always go together but we begin with half reactions:

     Example 3:   AsH3 ® As  (acidic)
                          As-3  ® As°    (oxidized)
                         AsH3® As + 3H+1 + 3e-1  (oxidation)

    Example 4:  VO3-1® V+2   (acidic)
                              V+5® V+2     (reduced)
                       VO3-1® V+2+ 3H2O
                      VO3-1+ 6H+1 + 3e-1 ® V+2 + 3H2O(reduction)

     Example 5:   U+4® UO2+1   (acidic)
                          U+4+2H2O ® UO2+1
                        U+4+ 2H2O ® UO2+1 4H+1 + 1e-1  (oxidation)

     Example 6:  MnO4-1® Mn+2    (acidic)
                          MnO4-1  ® Mn+2+ 4H2O
                        MnO4-1+  8H+1 +  5e-1® Mn+2 + 4H2 (reduction)

     But oxidation always accompanies reduction reaction. We now look at full (overall) reactions.

     Example 7:   MnO4-1+  Br-1 ® Mn+2  + Br2     (acidic)
                                 Mn+7® Mn+2  (reduced)
                            Br-1 ® Br°     (oxidized)
      Oxidation:       2Br-1®  Br2+  2e-1
      Reduction:    MnO4-1+  8H+1 +  5e-1® Mn+2+ 4H2O
     Multiply oxidation by 5 and reduction by 2 (e-1 lost must equal e-1 gained):
     [2Br-1 ®  Br2+  2e-1] 5
     [MnO4-1+  8H+1 + 5e-1® Mn+2+ 4H2O]2
     Oxidation:    10Br-1®  5Br2+  10e-1
     Reduction:  2MnO4-1+  16H+1 +  10e-1® 2Mn+2 + 8H2O
     Overall:       2MnO4-1+ 16H+1 + 10Br-1® 2Mn+2 +  5Br+ 8H2O

     Example 8:   Co  + NO3-1® Co+3  + NO2     (acidic)
                              Co° ® Co+3   (oxidized)
                          N+5 ® N+4   (reduced)
     Oxidation:   Co® Co+3  +  3e-1
     Reduction:   [NO3-1+ 2H+1 + 1e-1® NO2H2O] 3
     Overall:      Co+ 3NO3-1+ 6H+1® Co+3 + 3NO2 +  3H2O

   For REDOX under basic conditions, use OH-1/H2O to balance or first balance under acidic conditions
   followed by complete neutralization of H+1 with OH-1.

     Example 9:   MnO4-1® MnO2   (basic)
                          Mn+7 ® Mn+4  (reduced)
                         MnO4-1  + 4H+1 + 3e-1® MnO2+  2H2O         (4H+1 + 4OH-1 ® 4H2O)
                                             +4OH-1                          +4OH-1
                                     MnO4-1+ 4H2O + 3e-1 ® MnO2+ 4OH-1+ 2H2O (subtract 2H2O from each side)
                        MnO4-1+ 2H2O + 3e-1 ® MnO2+ 4OH-1

     Example 10:   ClO-1® Cl-1  (basic)
                           Cl+1 ® Cl-1    (reduced)
                         ClO-1 + 2H+1 + 2e-1®Cl-1+ H2O
                                   +2OH-1                     +2OH-1
                         ClO-1 + H2O + 2e-1® Cl-1 + 2OH-1

     Example 11:   Br2® 2BrO3-1  (basic)
                           Br° ® Br+5     (oxidized)
                           Br2 +  6H2O ® 2BrO3-1 + 12H+1 + 10e-1
                                 +12OH-1                  +12OH-1
                         Br2 +12OH-1  ® 2BrO3-1  + 6H2O + 10e-1

     Example 12:   Sn ® Sn(OH)4-2   (basic)
                         Sn  + 4OH-1® Sn(OH)4-2 + 2e-1  (reduced)

     Example 13:   Al  +  S  ® HS-1 + Al(OH)3      (basic)
                           Al° ® Al+3   (oxidized)
                            S° ® S-2   (reduced)
     Oxidation:     [Al + 3OH-1® Al(OH)3+ 3e-1]2
     Reduction:     S + H+1 + 2e-1® HS-1
                             +OH-1             +OH-1
                            [S + H2O + 2e-1 ® HS-1  + OH-1]3
     Overall:       2Al  +  3S + 3H2O + 3OH-1 ® 3HS-1 + 2Al(OH)3

     Example 14:   NO2-1  + Al  ® NH3 + Al(OH)4-1    (basic)
                            Al° ® Al+3   (oxidized)
                            N+3 ® N-3   (reduced)
     Oxidation:     [Al + 4OH-1® Al(OH)4-1 + 3e-1]2
     Reduction:  NO2-1 + 7H+1 + 6e-1 ® NH3+  2H2O
                                +7OH-1                     +7OH-1
                    [NO2-1 + 5H2O  + 6e-1 ® NH3+  7OH-1]
     Overall:     2Al + NO2-1 + 5H2O  + OH-1® 2Al(OH)4-1 + NH3