


HCl(aq)
H+1
+ Cl-1
produces H+1
in water
NH3(aq)
NH4+1
+ OH-1 produces
OH-1 in water
Although NH3 does not
contain OH-1, hydroxide ions form when
added to water.
Arrhenius acid and base neutralize each other to produce
salt and water:
HCl(aq) + NaOH(aq)
NaCl(aq)
+ H20(l)
H+1(aq) +
OH-1(aq)
H20(l)
Arrenhius theory most limited of the three theories since it requires reactions be aqueous and applies only to substances producing H3O+1 or OH-1.
2. Bronsted/Lowry
Theory
Johannes
Bronsted (1879-1947)
Thomas
Lowry (1874-1936)
In 1923, Bronsted (Danish) and Lowry (English) published
independent papers on the same subject. Unlike the Arrenhius theory,
their approach was not limited to aqueous solutions but for all proton
(H+) containing systems.
ACID:
Substance that can donate proton (H+1).
BASE: Substance
that can accept proton (must contain lone pair of electrons).
Acids may be cations, neutral molecules, or anions, while
bases may be anions or neutral molecules. Just as a reduction must
always accompany an oxidation, a proton donor (acid) must accompany a proton
acceptor (base). Once an acid transfers its proton it becomes the
conjugate base (CB) and once a base accepts the proton it becomes the conjugate
acid (CA). Since protons are always transferred in the Arrenhius
concept, all Arrhenius acid/base reactions are also Bronsted-Lowry acid/base
reactions.
But if water is not involved (HCl & NH3), the reaction
can be explained by Bronsted/Lowry concept and not Arrenhius. (Some
remarks on the concept of acids and bases by Bronsted).
HCl + NH3
NH4+1 + Cl-1
acid base
CA CB
Bronsted/Lowry expands Arrenhius
to include any proton transfer (water not requirement).
3. Lewis
Theory
Gilbert
Lewis (1875-1946)
Just as the Arrenhius theory did not support observations
of acid-base behavior in nonaqueous systems, the Bronsted-Lowry model excluded
nonprotonated systems. Lewis suggested
his theory in a 1923 book "Thermodynamics and the Free Energy of Chemical
Substances" and fully developed the theory in 1938.
ACID: Substance
that can accept a pair of electrons from another atom to form a new bond.
BASE: Substance
that can donate a pair of electrons to another atom to form a new bond.
The product of Lewis acid-base reaction referred to as
adduct. The proton itself can act as Lewis acid. Lewis
expands acid/base reactions to include many substances without H in formula.
F3B
+ :NH3
F3B:NH3
Explained by Lewis but not Arrenhius or BL
acid
base adduct
All Bronsted/Lowry acid/base reactions are also Lewis acid/base reactions.
Which theories can explain the
following?
HI + H2O
H3O+1
+ I-1 Explained
by all 3 theories
HI + NH3
NH4+1
+ I-1 Explained
by BL & Lewis
I2
+ NH3
NH3I+1
+ I-1 Explained
by Lewis
I2
+ Cl
ICl + I
Cannot be explained by
any of the theories
X:-1
+ Y+1
Y:X
Explained by Lewis but
not Arrenhius or BL
H2
+ Cl2
2HCl
Cannot be explained by
any of the theories!
Answer (a)-(e) based on the following equation:
XY
+ X2Z
X3Z+1
+ Y-1
(a) What is needed in the equation to be Arrenhius
acid-base reaction?
(b) What is needed in reaction to be Bronsted/Lowry
acid-base reaction?
(c) What is needed in reaction to be Lewis
acid-base reaction?
(d) Using the equation, why is Bronsted-Lowry
more general than Arrenhius?
(e) Using the equation, why is Lewis more
general than Bronsted-Lowry?
Answers: (a) X = H &
Z = O (b) X = H (c)
Z must possess lone pair in X2Z
(d) X2Z not limited to H2O
and X not limited to H (e) X not limited to H