Acid-Base Theories

1. Arrhenius Theory
     Svante Arrenhius (1857-1927)
Arrenhius proposed in his doctoral thesis (1883) that ionic compounds dissociate and can become free ions acting as separate entities in solution.  Faraday had assumed ions were produced only during electrolysis and required an electric current. Due to his revolutionary theory, Arrenhius received low rating for his dissertation (he was awarded Nobel Prize in 1903 for this work).
ACID: Substance that produces H+1 in water.
BASE:  Substance that produces OH-1 in water.

HCl(aq)H+1 + Cl-1        produces H+1 in water
NH3(aq)NH4+1  +  OH-1   produces OH-1 in water
Although NH3 does not contain OH-1, hydroxide ions form when added to water.
Arrhenius acid and base neutralize each other to produce salt and water:
HCl(aq) + NaOH(aq)NaCl(aq) + H20(l)
H+1(aq) + OH-1(aq) H20(l)

Arrenhius theory most limited of the three theories since it requires reactions be aqueous and applies only to substances producing H3O+1 or OH-1.

2. Bronsted/Lowry Theory
     Johannes Bronsted (1879-1947)
     Thomas Lowry (1874-1936)
In 1923, Bronsted (Danish) and Lowry (English) published independent papers on the same subject. Unlike the Arrenhius theory, their approach was not limited to aqueous solutions but for all proton (H+) containing systems.

ACID:  Substance that can donate proton (H+1).
BASE:  Substance that can accept proton (must contain lone pair of electrons).

Acids may be cations, neutral molecules, or anions, while bases may be anions or neutral molecules.  Just as a reduction must always accompany an oxidation, a proton donor (acid) must accompany a proton acceptor (base).  Once an acid transfers its proton it becomes the conjugate base (CB) and once a base accepts the proton it becomes the conjugate acid (CA).  Since protons are always transferred in the Arrenhius concept, all Arrhenius acid/base reactions are also Bronsted-Lowry acid/base reactions.
But if water is not involved (HCl & NH3), the reaction can be explained by Bronsted/Lowry concept and not Arrenhius.  (Some remarks on the concept of acids and bases by Bronsted).
HCl  +  NH NH4+1  +  Cl-1
acid      base       CA         CB
Bronsted/Lowry expands Arrenhius to include any proton transfer (water not requirement).

3. Lewis Theory
     Gilbert Lewis (1875-1946)
Just as the Arrenhius theory did not support observations of acid-base behavior in nonaqueous systems, the Bronsted-Lowry model excluded nonprotonated systems. Lewis suggested his theory in a 1923 book "Thermodynamics and the Free Energy of Chemical Substances" and fully developed the theory in 1938.

ACID:  Substance that can accept a pair of electrons from another atom to form a new bond.
BASE:  Substance that can donate a pair of electrons to another atom to form a new bond.

The product of Lewis acid-base reaction referred to as adduct. The proton itself can act as Lewis acid. Lewis expands acid/base reactions to include many substances without H in formula.
F3B  +  :NH3 F3B:NH3     Explained by Lewis but not Arrenhius or BL
acid      base        adduct

All Bronsted/Lowry acid/base reactions are also Lewis acid/base reactions.

Which theories can explain the following?
HI + H2OH3O+1 + I-1      Explained by all 3 theories
HI  +  NH3NH4+1 + I-1    Explained by BL & Lewis
I2 + NH3NH3I+1 + I-1      Explained by Lewis
I2  +  Cl ICl + I             Cannot be explained by any of the theories
X:-1 + Y+1Y:X                  Explained by Lewis but not Arrenhius or BL
H2 + Cl2 2HCl                Cannot be explained by any of the theories!

Answer (a)-(e) based on the following equation: XY + X2X3Z+1 + Y-1
(a) What is needed in the equation to be Arrenhius acid-base reaction?
(b) What is needed in reaction to be Bronsted/Lowry acid-base reaction?
(c) What is needed in reaction to be Lewis acid-base reaction?
(d) Using the equation, why is Bronsted-Lowry more general than Arrenhius?
(e) Using the equation, why is Lewis more general than Bronsted-Lowry?
Answers: (a) X = H  &  Z = O     (b) X = H      (c) Z must possess lone pair in X2Z
(d) X2Z not limited to H2O  and X not limited to H   (e) X not limited to H