Sir
William Hamilton (1805-1865) The Hamiltonian
function (1835) expresses rate of change in time for a set of moving particles.
It specifies total energy (kinetic & potential) in terms of dynamics,
position, and momentum of particles. Hamiltonians are a method for finding
the minimum value of a given equation and are used to calculate the path
of least action such as orbits and trajectories. Hamilton's (see
photo) unification of dynamics and optics has had a
lasting influence on mathematical physics, even though the full significance
of his work was not fully appreciated until after the rise of quantum mechanics.
Had Hamilton, often considered the "forgotten founder" of quantum
mechanics, been around in the 1920's, he surely would have seen the connection
between matrix mechanics and wave mechanics.
David
Hilbert (1862-1943) Hilbert (see
photo) was one of the outstanding mathematicians of the modern era.
He proposed 21 geometry axioms--the greatest influence in geometry since
Euclid (325 BC). Hilbert's work on infinite-dimensional space, later
called Hilbert space, proved invaluable for quantum mechanics. Today quantum
mechanics is said to be a theory set in "Hilbert Space." At the International
Congress of Mathematicians in Paris (1900) Hilbert presented the now famous
23
problems which he challenged 20th century mathematicians to solve.
In 1915 Hilbert discovered the correct field equations for general relativity
before Einstein but never claimed priority.
As professor of mathematics at the University of Göttingen, outstanding
scientists of the 20th century (Born, Heisenberg, Jordon, von Neumann to
name just a few) studied with Hilbert. Hilbert suggested to Heisenberg
that he find the differential equation that would correspond to his matrix
equations. Had he taken Hilbert's advice, Heisenberg may have discovered
the Schrödinger equation before Schrödinger.
When mathematicians proved Heisenberg's matrix mechanics and Schrödinger's
wave mechanics equivalent, Hilbert exclaimed, "Physics is obviously far
too difficult to be left to the physicists and mathematicians still think
they are God's gift to science."
Max
Planck (1858-1947) Most theoretical physicists
usually do their most important work by the age of 25 (Newton, Einstein,
Bohr, Heisenberg, Dirac, de Broglie, Pauli). This seems to be the
ideal age since there is time to learn enough while maintaining revolutionary
ideas. What is remarkable about Planck (see photo)
is that at age 42, he explained the puzzle of "black
body radiation." Any object with a higher temperature than its
surroundings loses heat by radiation. The hotter the object, the more radiation
it produces. Since a black body absorbs all frequencies, it should radiate
all frequencies equally. Instead, black bodies emit larger quantities
of some wavelengths than others. In 1900 Planck proposed that radiant heat
energy is emitted only in definite amount called quanta.
E = hn
n = frequency of light h
= 6.626x10-34 J•s
Planck maintained that only certain energies could appear and were
limited to whole-number multiples of hn.
Planck originally called h "quantum
of action" since the product of energy and time is known as action (based
on Hamilton's principle of least action). Today h
is known as Planck's constant and symbolizes the revolutionary new physics.
A young Max Planck was to give a lecture on radiant heat.
When he arrived he inquired as to the room number for the Planck lecture.
He was told, "You are much too young to be attending the lecture of the
esteemed professor Planck."
Albert
Einstein (1879-1955) 1905 was a
good year for Einstein (see photo). He
managed to solve three of the outstanding problems of physics: the photoelectric
effect, Brownian motion, and special theory of relativity. These
three publications have become known as the "Einstein trilogy."
Prior to 1905 researchers noted that current was proportional to the intensity
of light striking the surface of a metal. The maximum kinetic energy of
electron does not depend on intensity but rather on the frequency of the
light. Einstein realized Planck's idea of light appearing as quanta
(bundles) was the key to understanding this photoelectric mystery.
If the wavelength is short enough, the electron cannot escape. The important
thing is the energy of the bundle and not number of bundles (brightness).
The photoelectric effect is recognized as the first scientific work utilizing
quantum mechanics.
Einstein could never accept some of the revolutionary ideas of quantum
mechanics ("God does not play dice"). When reminded in 1927 that
he revolutionized science 20 years earlier, Einstein replied, "A good joke
should not be repeated too often."
Niels
Bohr (1885-1962) In 1913 Bohr (see
photo) was the first to apply the quantum theory to atomic structure.
The most impressive result of the so-called Bohr theory was the way it
accounted for the series of lines observed in the spectrum of light emitted
by atomic hydrogen. Bohr was able to determine the frequencies of these
spectral lines to considerable accuracy by expressing them in terms of
the charge and mass of the electron and Planck's constant. To do this,
Bohr also postulated that an atom would not emit radiation while it was
in one of its stable states but rather only when it made a transition between
states. The frequency of the emitted radiation would be equal to the difference
in energy between those states divided by Planck's constant. This meant
that the atom could neither absorb nor emit radiation continuously but
only in finite steps or quantum jumps. It also meant that the various frequencies
of the radiation emitted by an atom were not equal to the frequencies with
which the electrons moved within the atom. This was a bold idea that
some of Bohr's contemporaries found difficult to accept.
In 1916 Bohr was appointed professor to the newly created chair of
theoretical physics at the University of Copenhagen and in 1921 the Bohr
Institute opened with Bohr as its director. The Bohr
Institute became a leading center for quantum physics with young theoretical
physicists from all over the world (Pauli, Heisenberg, Dirac, Oppenheimer,
and Gamow to name just a few) coming to Copenhagen to work with Bohr.
Sometimes the young physicists would sit at sidewalk cafes discussing the
latest quantum theories while applying amusing scientific methods such
as the following to describe the women of Copenhagen as they passed by.
You can't stop looking
You can stop but it hurts
It makes no difference whether you look
You can look but it hurts
You can't look
Werner
Heisenberg (1901-1976) Making use
of matrix algebra, Heisenberg (see photo) developed
a system called matrix mechanics (1925). It consisted of an array
of quantities which when appropriately manipulated gave the observed frequencies
and intensities of spectral lines. The consequence of Heisenberg's
work is his revolutionary (1927)
uncertainty
principle: DqDp
> h
The uncertainty of position (Dq)
of an electron in an atom multiplied by the uncertainty of its momentum
(Dp) must
be greater than Planck's constant (h).
The uncertainty principle tells us that all observable quantities are subject
to changes determined by Planck's constant and we cannot know position
and momentum simultaneously. While a photon will not disturb an object
like a house, it does alter position and momentum when bounced off an electron.
If all this has you confused, then
see the movie "Heisenberg May Have Slept Here."
Louis
de Broglie (1892-1987) As
an undergraduate de Broglie (see photo) studied
medieval history. During World War I he served in a
field radio communication unit and this changed his interest from Gothic
cathedrals to electromagnetic waves.
After the war de Broglie did his doctoral thesis in what has become known
as "de Broglie waves." In 1924 de Broglie speculated that nature
did not single out light as the only entity to exhibit wave-particle duality.
He proposed that ordinary particles such as electrons could also exhibit
wave characteristics in certain circumstances. de Broglie assumed
that an electron has associated with it a system of "matter waves."
These waves possess crests that disappear at one point and appear an instant
later at another point. The distance between successive crests (l)
is the de
Broglie wavelength calculated from l=h/mv,
where h is Planck's constant and mv
is momentum. The following is taken from Thirty Years
that Shook Physics by George Gamow:
At our first meeting we started talking physics although de Broglie
did not speak any English and my French was rather poor. But somehow
I managed to convey to him what I wanted to say and to understand his comments.
A year later I was in the audience in London when de Broglie delivered
a brilliant lecture in perfect English. Then I understood another
of his principles: When foreigners come to France, they must speak
French.
Erwin
Schrödinger (1887-1961) Adopting
the proposal by de Broglie that particles of matter have dual nature and
in some situations act like waves, Schrödinger (see
photo) produced the basic equation of quantum mechanics (1926).
The Schrödinger equation treats electrons as matter waves:
The only problem with Schrödinger's equation was his interpretation
of the matter wave was wrong. He described y
as the density distribution--some
regions rich in electron matter while others scarce. But it was Max
Born who figured out what the equation actually predicts.
In 1944 Schrödinger wrote a short book entitled "What is Life?"
Schrödinger suggests that one of life's essential features is the
storage of a genetic code passed from parent to offspring. Because it had
to fit in a single cell, Schrödinger suggests the code is written
at the molecular level. Schrödinger's book had a pronounced influence
on Crick & Watson, discoverers of DNA.
The following is taken from The God Particle by Leon Lederman:
Leaving his wife at home, Schrödinger booked a villa in the
Swiss Alps for two weeks, taking with him his notebooks, two pearls, and
an old Viennese girlfriend. Schrödinger's self-appointed mission was
to save the patched-up, creaky quantum theory of the time. The Viennese-born
physicist placed a pearl in each ear to screen out any distracting noises.
Then he placed the girlfriend in bed for inspiration. Schrödinger
had his work cut out for him. He had to create a new theory and keep
the lady happy. Fortunately, he was up to the task.
Max
Born (1882-1970)
In 1926, after his student Werner Heisenberg had formulated the first laws
of quantum mechanics, Born (see photo) collaborated
with him to develop the mathematical formulation that would adequately
describe it. When Schrödinger put forward his quantum mechanical wave
equation, Born showed that the solution of the equation has a statistical
meaning of physical significance. Born's interpretation of the wave equation
proved to be of fundamental importance in the new theory of quantum mechanics.
Schrödinger believed that the electron was spread out in space and
its density given by the value of y2.
Almost immediately Born proposed what is now the accepted interpretation:
y2
gives the probability
density of finding the electron. The distinction between the two interpretations
is important. If y2
is small at a particular position, the original interpretation implies
that a small fraction of an electron will always be detected there. In
Born's interpretation, nothing will be detected there most of the time,
but when something is observed, it will be a whole electron. The concept
of the electron as a point particle moving in a well-defined path around
the nucleus is replaced in wave mechanics by clouds that describe the probable
locations
of electrons in different states. Born's probability density is perhaps
the most dramatic change in viewing our world since Newton and gravity.
Other notable contributions by Born include Born-Haber
cycle and Olivia
Newton-John.
The following is taken from Men Who Made a New Physics by Barbara
Cline:
Born has been described as a moody and impulsive person. He would
tell his student, "You must not mind my being rude. I have a resistance
against accepting something new. I get angry and swear but always
accept after a time if it is right."
Wolfgang
Pauli (1900-1958) Pauli (see
photo) proposed a new quantum theory property (1925) called "two-valuedness."
Goudsmit
and Uhlenberg identified this fourth quantum number as electron spin.
The exclusion principle is now stated as, "No two electrons in an atom
can have the same set of four quantum numbers."
The exclusion principle subsequently has been modified to include a
whole class of particles of which the electron is only one member. Subatomic
particles fall into two classes: particles obeying the Pauli exclusion
principle are fermions and all others are bosons. When in a closed system,
such as an atom for electrons or a nucleus for protons and neutrons, fermions
are distributed so that a given state is occupied by only one at a time.
Undergraduate Pauli moderated an Einstein lecture. After Einstein's
response to a question Pauli summarized with, "What Einstein says
is not so stupid!"
When distinguished physicist Paul Ehrenfest told Pauli that
he liked Pauli's publications better than he liked Pauli, Pauli replied,
"That's odd, I feel the exact opposite about you!"
Paul
Dirac (1902-1984) Dirac (see
photo) laid the foundations for quantum electrodynamics (1927) with
his discovery of an equation incorporating both the quantum theory
and the theory of special relativity. Dirac showed that the correct
relationship between mass and energy was not Einstein's equation (E = mc2)
but actually E2 = m2c4.
When solving Dirac's equation, E =mc2
as well as E = -mc2
But how can energy of an electron be negative? Dirac predicted
the existence of electrons with positive charge (antielectron or positron).
In 1932 Carl Anderson detected positrons. Dirac also predicted every
particle possesses an antiparticle (antiproton, antineutron, etc.).
Local Interest: Dirac was professor of physics at Florida State University
from 1971-1984. The Dirac
Science Library is named after him.
During a question and answer period after a lecture Dirac gave at
the University of Toronto, an audience member raised his hand and said,
"Professor Dirac, I do not understand how you derived the formula
on the top left side of the blackboard."
"That is not a question," snapped Dirac, "it is a statement.
Next question, please."
John
von Neumann (1903-1957)
Early quantum theory had two approaches: Matrix mechanics proposed
by Heisenberg and wave mechanics developed by Schrödinger. Heisenberg
found the physical ideas of Schrödinger's theory "disgusting,"
and Schrödinger was "discouraged and repelled" by lack of visualization
in Heisenberg's method.
von Neumann (see photo) was considered the
brightest young mathematician in Europe. After hearing Heisenberg
lecture on matrix mechanics, von Neumann decided to develop his own version
of quantum mechanics--the matrices of Heisenberg were "too imprecise."
In his book (1932), The mathematical Foundations of Quantum Mechanics,
von Neumann invented operator
theory (now called Neumann algebras) to explain certain aspects of
quantum mechanics. Largely because of his work, quantum physics and
operator theory can be viewed as two aspects of the same subject. von Neumann's
new mathematics proved Schrödinger and Heisenberg theories equivalent
mathematically. Schrödinger's wave mechanics eventually became the
method of choice because it is less abstract and easier to understand than
Heisenberg's matrix mechanics.
In 1933 von Neumann solved Hilbert's
fifth problem, the case of compact groups. Although he never won Nobel
Prize or gained world-wide fame, von Neumann was one of the truly outstanding
mathematician/scientists of the 20th century.
Solvay
Conference Participants (1927)
The 1927 Solvay Conference, held in Belgium, was attended by the
world's most notable physicists to discuss the newly formulated quantum
theory. Of the 12 individuals cited here in the History of Quantum
Mechanics, only the three mathematicians were not in attendance: William
Hamilton was dead, John von Neumann did not publish his book until 1932,
and David Hilbert ("physics far too difficult for physicists") probably
wasn't invited.