
Unfortunately, thallium was not discovered by my great-grandfather
Ezra Thall but by British chemist/physicist William
Crookes. At the tender age of 25, Crookes inherited a fortune
from his father and proceeded to devote the rest of his life pursuing scientific
research (Ezra Thall would have pursued other interests had he inherited
the fortune). Crookes is best known for work on electrical discharges
through rarefied air that led him to observe the dark space around the
cathode (appropriately called Crookes dark space). In the process
he developed the Crookes
tube or cathode ray tube. Crookes was knighted in 1897 and
hence the "Sir." Physics Nobel Laureate J.J. Thomson modified
Crookes' tube and in 1897 discovered the electron but that's another story.
Back to thallium and spectrum analysis.
Spectrum Analysis
Around 1859 at the University of Heidelberg in Germany,
Robert
Bunsen (1811-1899) and Gustav
Kirchhoff (1824-1887) developed what has become known as spectrum
analysis (use of light or electromagnetic radiation to analyze substances).
Gustav Kirchhoff had the brilliant insight to use a prism to separate the
light of heated substances into constituent rays, thus the fledgling science
of spectroscopy, which would develop into a vital tool for chemical analysis,
was born. Bunsen and Kirchhoff developed the spectroscope shown below from
a prism, cigar box, and two ends of old telescopes.
Using this instrument, Bunsen/Kirchhoff were able to
identify elements since each element has its own unique atomic spectrum
as illustrated for hydrogen, helium, lithium, and mercury:
Bunsen/Kirchhoff perfected the technique by noting that
the lines became more distinct at higher temperatures and lower luminescence
of the flame. The instrument proved to be of
tremendous importance not only in chemical analysis but in the discovery
of new elements. In 1861 Bunsen/Kirchhoff
announced the discovery of cesium
(Latin
"caesium" meaning sky blue) in the following passage:
"Supported
by unambiguous results of the spectral-analytical method, we believe
we can state rightnow that there is a fourth metal in the alkali group
besides
potassium, sodium, and lithium, and ithas a simple characteristic spectrum
like
lithium; a metal that shows only two lines in our apparatus: a
faint blue one,
almost coinciding with strontium and another blue one a little further
to the violet
end of the spectrum and as strong and as clearly defined as the lithium
line."
A few months after the cesium discovery, Bunsen/Kirchhoff
discovered another new alkali metal. This element was named rubidium
from the Latin "rubidus" meaning darkest red color.
Bunsen/Kirchhoff
published Chemical
Analysis by Observation of Spectra and undoubtedly Crookes was
aware of their work. So when Crookes (1861) noted a bright green
spectral line resulting from heating selenium minerals, he realized immediately
that the line represented a new element. Crookes, following the naming
trend set by Bunsen/Kirchhoff, called the element thallium from the Greek
word "thallos" meaning green shoot. After isolating thallium, Crookes
studied its properties and determined the atomic weight.
Eventually the puzzle of atomic spectra was explained
by Niels Bohr. When heated, electrons in atoms jump to a higher energy
level and upon returning to their normal energy level, emit energy in the
form of electromagnetic radiation (light). The atomic spectra wavelengthsprovided
crucial data for determining atomic structure.
Properties
Thallium is the heaviest of the Group IIIa elements and
usually takes on charge of +1 (Tl+1 resembles
the heavier alkali metal ions). Tl+3
compounds are readily reduced to Tl+1.
Tl° [Xe]
6s2 4f14
5d10 6p1
Tl+1
[Xe] 6s2 4f14
5d10 6p°
Tl+3
[Xe] 6s° 4f14 5d10
6p°
Like lead, thallium is a soft, low-melting element of low tensile strength. Freshly cut thallium has a metallic luster that dulls to bluish gray upon exposure to air. Thallium dissolves slowly in hydrochloric acid and dilute sulfuric acid and rapidly in nitric acid.
| Melting Point | 303.5°C |
| Boiling Point | 1457°C |
| Density | 11.85 g/mL |
| Atomic Radius | 2.08 A |
| Heat of Vaporization | 164 kJ/mol |
| Ionization Potential | 6.11 V |
| Ionization Potential | 4.14 kJ/mol |
| Electronegativity | 2.04 |
| Specific Heat | 0.13 J/g/K |
203Tl (29.50%) 205Tl (70.50%)
Traces of short-lived isotopes occur as decay products
in three natural radioactive disintegration series:
Uranium series produces 206Tl
& 210Tl
Thorium series produces 208Tl
Actinium series produces 207Tl
| Isotope | Half Life |
| Tl-200 | 1.08 days |
| Tl-201 | 3.03 days |
| Tl-202 | 12.23 days |
| Tl-203 | stable |
| Tl-204 | 3.78 years |
| Tl-205 | stable |
| Tl-206 | 4.2 minutes |
| Tl-207 | 4.77 minutes |
| Tl-208 | 3.05 minutes |
| Tl-209 | 2.2 minutes |
| Tl-210 | 1.3 minutes |
Uses
Uses for thallium include thallium-201 stress test, rodenticides, photocells,
infrared detectors, low melting glasses, and treatment for skin infections