| 104-112 add to [Rn] 5f14 | 113-121 add to [Rn] 5f14 6d10 |
| 104 7s2 6d2 | 113 7s2 7p1 |
| 105 7s2 6d3 | 114 7s2 7p2 |
| 106 7s2 6d4 | 115 7s2 7p3 |
| 107 7s2 6d5 | 116 7s2 7p4 |
| 108 7s2 6d6 | 117 7s2 7p5 |
| 109 7s2 6d7 | 118 7s2 7p6 |
| 110 7s2 6d8 | 119 7s2 7p1 8s1 |
| 111 7s2 6d9 | 120 7s2 7p1 8s2 |
| 112 7s2 6d10 | 121 7s2 7p1 8s2 7d1 |
Until 1997, the International Union of Pure and Applied Chemistry (IUPAC) recommended different names for elements 104-109 than those suggested by American Chemical Society (ACS). IUPAC and ACS currently differ only for elements 105 & 107.
| Element # | IUPAC until 1997 | Current IUPAC | ACS |
| 104 | unnilquadrium | rutherfordium (Rf) | rutherfordium |
| 105 | unnilpentium | dubium (Db) | hahnium (Ha) |
| 106 | unnilhexium | seaborgium (Sg) | seaborgium |
| 107 | unnilseptium | bohrium (Bh) | nielsbohrium (Ns) |
| 108 | unniloctium | hassium (Hs) | hassium |
| 109 | unnilennium | meitnerium (Mt) | meitnerium |
Ernest
Lawrence (1901-1958)
When Lawrence joined the physics faculty at Berkeley in 1928, the hottest
topic in physics was bombarding the atom's nucleus to see what new particles
it might produce. Lawrence read about a theoretical linear accelerator
that was too long to be practicle. Lawrence knew that a magnetic
field would deflect the charged particles into a curved path. By making
the particles go in a spiral, he could boost the energy bit by bit each
time they circled an electrode The university gave Lawrence approval
and in 1930 the cyclotron
was born. This new tool launched the modern era of high-energy physics.
In 1961, element 103 was and named in his honor.
Otto
Hahn (1879-1968)
In 1938, Otto Hahn repeated Fermi's experiments of bombarding uranium
with neutrons. Hahn and co-worker Fritz Strassmann discovered three
isotopes of barium had been produced. This was incredible because
the mass of barium is about half of uranium and no known reaction could
explain such a huge change. Hahn, a chemist, could not offer an explanation.
He wrote to Lise Meitner, his longtime collaborator, describing his findings
and asking "Perhaps you can suggest some fantastic explanation," which
she explained as nuclear fission. Nevertheless, despite the contributions
of Strassmann and Meitner, it was Hahn who was awarded the 1945 Nobel Prize
in chemistry for the discovery. Unfortunately, Hahn was not at the
awards ceremony to receive his prize. At the time he learned of the award,
he was being held by the British who were seeking information from him
about the failed German effort to develop an atomic bomb. As the chairman
of the Nobel Committee for Chemistry reported "Professor Hahn has informed
us that he is regrettably unable to attend this ceremony."
Glenn
Seaborg (1912-1999)
After graduating from UCLA with a degree in chemistry in 1934, Seaborg
did graduate work at Berkeley under Gilbert Lewis (acid-base theory) and
completed his Ph.D. in 1937 under Ernest Lawrence (fast neutrons).
During World War II he headed the group which devised the chemical extraction
processes used in the production of plutonium for the Manhattan Project.
Besides plutonium, Seaborg discovered americium, curium, berkelium, californium,
einsteinium, fermium, mendelevium and nobelium. In 1944 Seaborg formulated
the actinide series placing elements 90-103 at the bottom of periodic table.
For discoveries of the transuranium elements, Seaborg was awarded
the 1951 Nobel Prize in chemistry. Seaborgium, atomic number 106,
represents the first time an element had been named after a living person.
Lise
Meitner (1878-1968)
Meitner, first woman to receive doctorate in physics from the University
of Vienna, began work in 1907 with Otto Hahn at the University of Berlin.
They studied radioactive substances for the next 30 years; she did the
physics and he the chemistry. Together and independently they achieved
important results in the new field of nuclear physics including techniques
for purifying radioactive material, discovering the element protactinium
(#91), and explaining how gamma rays eject orbital electrons.
Leaving Germany in 1938 because of her Jewish ancestry, Meitner obtained
an appointment at the Physics Institute in Stockholm. Otto Hahn,
who was still in Germany, repeated some of Fermi's early experiments. He
wrote Meitner reporting how bombarding uranium with neutrons produced radioactive
barium. Meitner, realizing that uranium had been split, made calculations
showing the formation of barium, krypton, additional neutrons, and energy.
When Leo Szilard at Columbia
University discovered that more neutrons were produced than used in the
fission, he convinced Einstein to write President Franklin Roosevelt (see
letter) to set up program for creating Atomic Bomb. The first
fission bomb resulted from bombarding 235U with a neutron to
form 236U; 236U immediately barium, krypton,
3 additional neutrons, and enormous amount of energy. The 3 neutrons
can strike three 235U nuclei and generate 9 neutrons, which
can generate 27 neutrons, and so on (chain reaction).
235U + 0n ®
236U
® 141Ba
+ 92Kr + 3 1n
+ energy
Meitner & Hahn named the process "nuclear fission" and reported
the results in the journal Nature (1939). In 1945 the Nobel
Prize in Chemistry was awarded to Otto Hahn for the discovery of nuclear
fission. Probably due to Meitner's leaving Germany, the Nobel committee
failed to understand her part in the work. Lise Meitner was probably
the most significant woman scientist of the 20th century.